<font face="Arial, Verdana">Ok so it's processed correctly but for some reason the image URLs are off. While that's certainly ugly and should be fixed, it has nothing to do with the original problem where your ghostscript and imagemagick are not being detected correctly. </font>
In your PHP test script you have
exec('/opt/bin/identify 2> /dev/null', $va_output, $vn_return);echo $vn_return;
<font face="DIN17SBOP-Regular, Helvetica Neue">and you get a return val of 0, which should mean it ought to be detected. All we do is check the return value. Is your external_applications.conf set like this?</font>
<font face="DIN17SBOP-Regular, Helvetica Neue"></font>
imagemagick_path = /opt/bin<font face="DIN17SBOP-Regular, Helvetica Neue"></font>
The only other thing I can think of is that for some reason your external_applications.conf is not readable or somehow fails to parse without giving an error message. Or do you by any chance have a external_applications.conf in app/conf/local? That one would override the one in app/conf.
Also, I noticed your UI is in German. Can I ask which museum you're working for? We're always psyched about new users here in Germany (I'm in Berlin) ;-)